The only issues you'll have with alignments/camber when slammed is if your rear arms/ball joints are worn.

So if you have a ton of miles and are upgrading to coilovers I'd also do the rear ball joints and the control arms with new ones so that you can get a good alignment when done

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2018 Ram 2500 6.7L Cummins 68RFE
19k miles -Bright White/Black - Big Horn Sport - Crew Cab Short Bed
2013 X5 35D (CEO's) - Born on 5/17/2013 -
82k miles - Alpine White/Cinnamon Brown/Premium Pkg, Sport Activity/Premium Pkg and Sound/20" Style 214/Running Boards