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My guess is that you were leaking coolant on start-up... and maybe before that.
In CA, I bet this car has seen some traffic... I would check to see if both fans are working..Do the newspaper test on the mech fan... The fans do fail and will not generally give a code.
I have done a head gasket on my '05 3.0...It's easy...even for a first-timer. We can talk you through it.
I rent the time-sert tools.
Up to you whether to buy another one..They are pretty cheap...But if your X5 is in good shape and you like it, I would fix it.
You can try and put more coolant in it and see if it holds, but I think the head has to come off... it will give you a chance to replace coolant pipes and a few other things.. Compression test might not tell you much...I had coolant pooling in cylinder 6 yet I had good compression on all 6 cylinders. I think swabbing the cylinders for coolant the morning after running it to op temp is a better test.
Blocks can and do warp, but the likely issue in your case is that the head is warped and the block is okay...
Dive in, man...
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